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Free Radical Research Communications Volume 10, 1990 - Issue 1-2
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Original Article

Fluorescence Detection of Carbon-Centered Radicals in Aqueous Solution

David J. Kieber Woods Hole Oceanographic Institution, Chemistry Department, Woods Hole, Massachusetts, 02543, USA
&
Neil V. Blough Woods Hole Oceanographic Institution, Chemistry Department, Woods Hole, Massachusetts, 02543, USA
Pages 109-117 | Published online: 07 Jul 2009

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David J. Kieber, Carl G. Johnson & Neil V. Blough. (1992) Mass Spectrometric Identification of the Radical Adducts of a Fluorescamine-Derivatized Nitroxide. Free Radical Research Communications 16:1, pages 35-39.
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Articles from other publishers (54)

Danielle M. Le Roux, Leanne C. Powers & Neil V. Blough. (2021) Photoproduction Rates of One-Electron Reductants by Chromophoric Dissolved Organic Matter via Fluorescence Spectroscopy: Comparison with Superoxide and Hydrogen Peroxide Rates. Environmental Science & Technology 55:17, pages 12095-12105.
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Jiaqian Sun, Jianzhong Ma, Lushi Lian, Shuwen Yan & Weihua Song. (2020) Photochemical Formation of Methylhydroperoxide in Dissolved Organic Matter Solutions. Environmental Science & Technology 55:2, pages 1076-1087.
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Stefanos Giannakis, María Inmaculada Polo López, Dorothee Spuhler, Jose Antonio Sánchez Pérez, Pilar Fernández Ibáñez & César Pulgarin. (2016) Solar disinfection is an augmentable, in situ -generated photo-Fenton reaction—Part 1: A review of the mechanisms and the fundamental aspects of the process. Applied Catalysis B: Environmental 199, pages 199-223.
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Yi Zhang & Neil V. Blough. (2016) Photoproduction of One-Electron Reducing Intermediates by Chromophoric Dissolved Organic Matter (CDOM): Relation to O 2 – and H 2 O 2 Photoproduction and CDOM Photooxidation . Environmental Science & Technology 50:20, pages 11008-11015.
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Mohamad Sleiman, Hugo Destaillats & Lara A. Gundel. (2013) Solid-phase supported profluorescent nitroxide probe for the determination of aerosol-borne reactive oxygen species. Talanta 116, pages 1033-1039.
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Yi Zhang, Rossana Del Vecchio & Neil V. Blough. (2012) Investigating the Mechanism of Hydrogen Peroxide Photoproduction by Humic Substances. Environmental Science & Technology 46:21, pages 11836-11843.
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Elizabeth E. Dahl, Elise M. Heiss & Kevin Murawski. (2012) The effects of dissolved organic matter on alkyl nitrate production during GOMECC and laboratory studies. Marine Chemistry 142-144, pages 11-17.
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Karim Michail & Arno G. Siraki. (2012) Post-Trapping Derivatization of Radical-Derived EPR-Silent Adducts: Application to Free Radical Detection by HPLC/UV in Chemical, Biochemical, and Biological Systems and Comparison with EPR Spectroscopy. Analytical Chemistry 84:15, pages 6739-6746.
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David Bardelang, Micaël Hardy, Olivier Ouari & Paul Tordo. 2012. Encyclopedia of Radicals in Chemistry, Biology and Materials. Encyclopedia of Radicals in Chemistry, Biology and Materials.
Yulia B. Borozdina, Valentin Kamm, Frédéric Laquai & Martin Baumgarten. (2012) Tuning the sensitivity of fluorophore–nitroxide radicals. Journal of Materials Chemistry 22:26, pages 13260.
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Lucy J. Carpenter, Stephen D. Archer & Rachael Beale. (2012) Ocean-atmosphere trace gas exchange. Chemical Society Reviews 41:19, pages 6473.
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Guo-Ping Yan, Kathryn E. Fairfull-Smith, Craig D. Smith, Graeme R. Hanson & Steven E. Bottle. (2012) Porphyrin containing isoindoline nitroxides as potential fluorescence sensors of free radicals. Journal of Porphyrins and Phthalocyanines 15:04, pages 230-239.
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James P. Blinco, Kathryn E. Fairfull-Smith, Benjamin J. Morrow & Steven E. Bottle. (2011) Profluorescent Nitroxides as Sensitive Probes of Oxidative Change and Free Radical Reactions. Australian Journal of Chemistry 64:4, pages 373.
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Angela G. Rincón, Marcelo I. Guzmán, M. R. Hoffmann & A. J. Colussi. (2009) Optical Absorptivity versus Molecular Composition of Model Organic Aerosol Matter. The Journal of Physical Chemistry A 113:39, pages 10512-10520.
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Min Jia, Yu Tang, Yiu-Fai Lam, Sarah A. Green & Neil V. Blough. (2009) Prefluorescent Nitroxide Probe for the Highly Sensitive Determination of Peroxyl and Other Radical Oxidants. Analytical Chemistry 81:19, pages 8033-8040.
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Olivier M. Lardinois, David A. Maltby, Katalin F. Medzihradszky, Paul R. Ortiz de Montellano, Kenneth B. Tomer, Ronald P. Mason & Leesa J. Deterding. (2009) Spin Scavenging Analysis of Myoglobin Protein-Centered Radicals Using Stable Nitroxide Radicals: Characterization of Oxoammonium Cation-Induced Modifications. Chemical Research in Toxicology 22:6, pages 1034-1049.
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Judit Bartalis, Yi-Lei Zhao, Jason W. Flora, John B. PaineIIIIII & Jan B. Wooten. (2008) Carbon-Centered Radicals in Cigarette Smoke: Acyl and Alkylaminocarbonyl Radicals. Analytical Chemistry 81:2, pages 631-641.
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Elizabeth E. Dahl & Eric S. Saltzman. (2008) Alkyl nitrate photochemical production rates in North Pacific seawater. Marine Chemistry 112:3-4, pages 137-141.
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Yusuke Suzuki & Toshiyuki Katagi. (2008) Novel Fluorescence Detection of Free Radicals Generated in Photolysis of Fenvalerate. Journal of Agricultural and Food Chemistry 56:22, pages 10811-10816.
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Kathryn E. Fairfull-Smith & Steven E. Bottle. (2008) The Synthesis and Physical Properties of Novel Polyaromatic Profluorescent Isoindoline Nitroxide Probes. European Journal of Organic Chemistry 2008:32, pages 5391-5400.
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Qing Zhu, Yuxiang Lian, Sunita Thyagarajan, Steven E. Rokita, Kenneth D. Karlin & Neil V. Blough. (2008) Hydrogen Peroxide and Dioxygen Activation by Dinuclear Copper Complexes in Aqueous Solution: Hydroxyl Radical Production Initiated by Internal Electron Transfer. Journal of the American Chemical Society 130:20, pages 6304-6305.
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Sergei V. Chetyrkin, Missy E. Mathis, Amy-Joan L. Ham, David L. Hachey, Billy G. Hudson & Paul A. Voziyan. (2008) Propagation of protein glycation damage involves modification of tryptophan residues via reactive oxygen species: inhibition by pyridoxamine. Free Radical Biology and Medicine 44:7, pages 1276-1285.
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James P. Blinco, John C. McMurtrie & Steven E. Bottle. (2007) The First Example of an Azaphenalene Profluorescent Nitroxide. European Journal of Organic Chemistry 2007:28, pages 4638-4641.
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Gertz I. Likhtenstein, Kazuyuki Ishii & Shin’ichi Nakatsuji. (2007) Dual Chromophore-Nitroxides: Novel Molecular Probes, Photochemical and Photophysical Models and Magnetic Materials. Photochemistry and Photobiology 83:4, pages 871-881.
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E. E. Dahl, S. A. Yvon-Lewis & E. S. Saltzman. (2007) Alkyl nitrate (C 1 -C 3 ) depth profiles in the tropical Pacific Ocean . Journal of Geophysical Research 112:C1.
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Nobuaki Soh. (2006) Recent advances in fluorescent probes for the detection of reactive oxygen species. Analytical and Bioanalytical Chemistry 386:3, pages 532-543.
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Martin Danko, Štefan Chmela & Pavol Hrdlovič. (2006) Synthesis, photochemical stability and photo-stabilizing efficiency of probes based on benzothioxanthene chromophore and Hindered Amine Stabilizer. Polymer Degradation and Stability 91:5, pages 1045-1051.
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M. I. Guzmán, A. J. Colussi & M. R. Hoffmann. (2006) Photoinduced Oligomerization of Aqueous Pyruvic Acid. The Journal of Physical Chemistry A 110:10, pages 3619-3626.
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Daniel J. Keddie, Therese E. Johnson, Dennis P. Arnold & Steven E. Bottle. (2005) Synthesis of profluorescent isoindoline nitroxides via palladium-catalysed Heck alkenylation. Organic & Biomolecular Chemistry 3:14, pages 2593.
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Andrea Ricci, Michelle N. Chrétien & J. C. Scaiano. (2004) Base-Catalyzed Ship-in-a-Bottle Synthesis of a Prefluorescent, Zeolite-Incorporated Sensor for Monitoring Radical Processes in Zeolites. Chemistry of Materials 16:13, pages 2669-2674.
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Chris Coenjarts, Olga García, Laura Llauger, J. Palfreyman, Anne L. Vinette & J. C. Scaiano. (2002) Mapping Photogenerated Radicals in Thin Polymer Films:  Fluorescence Imaging Using a Prefluorescent Radical Probe. Journal of the American Chemical Society 125:3, pages 620-621.
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Martin Danko, Štefan Chmela & Pavol Hrdlovič. (2003) Photochemical stability and photostabilizing efficiency of anthracene/hindered amine stabilizers in polymer matrices. Polymer Degradation and Stability 79:2, pages 333-343.
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Pavol Hrdlovič, Martin Danko & Štefan Chmela. (2002) Preparation, spectral characteristics and photolytic stability of anthracene-hindered amine probes: influence of the medium. Journal of Photochemistry and Photobiology A: Chemistry 149:1-3, pages 207-216.
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Tal Offer & Amram Samuni. (2002) Nitroxides inhibit peroxyl radical-mediated DNA scission and enzyme inactivation. Free Radical Biology and Medicine 32:9, pages 872-881.
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P Parkhomyuk-Ben Arye, N Strashnikova & G.I Likhtenshtein. (2002) Stilbene photochrome-fluorescence-spin molecules: covalent immobilization on silica plate and applications as redox and viscosity probes. Journal of Biochemical and Biophysical Methods 51:1, pages 1-15.
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T M FlickerS A Green. (2001) Comparison of gas-phase free-radical populations in tobacco smoke and model systems by HPLC.. Environmental Health Perspectives 109:8, pages 765-771.
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Xiao-Feng Yang & Xiang-Qun Guo. (2001) Study of nitroxide-linked naphthalene as a fluorescence probe for hydroxyl radicals. Analytica Chimica Acta 434:2, pages 169-177.
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Graeme Moad, Devon A. Shipp, Trevor A. Smith & David H. Solomon. (1999) Measurements of Primary Radical Concentrations Generated by Pulsed Laser Photolysis Using Fluorescence Detection. The Journal of Physical Chemistry A 103:33, pages 6580-6586.
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Beibei Li, Peter L. Gutierrez & Neil V. Blough. 1999. Oxidants and Antioxidants Part B. Oxidants and Antioxidants Part B 202 216 .
Sarah E. Herbelin & Neil V. Blough. (1998) Intramolecular Quenching of Excited Singlet States in a Series of Fluorescamine- Derivatized Nitroxides. The Journal of Physical Chemistry B 102:42, pages 8170-8176.
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Pamela P. Vaughan & Neil V. Blough. (1998) Photochemical Formation of Hydroxyl Radical by Constituents of Natural Waters. Environmental Science & Technology 32:19, pages 2947-2953.
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Willer H. Pos, Daniel D. Riemer & Rod G. Zika. (1998) Carbonyl sulfide (OCS) and carbon monoxide (CO) in natural waters: evidence of a coupled production pathway. Marine Chemistry 62:1-2, pages 89-101.
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Murali C. Krishna, William DeGraff, Olga H. Hankovszky, Cecília P. Sár, Tamás Kálai, József Jekő, Angelo Russo, James B. Mitchell & Kálmán Hideg. (1998) Studies of Structure−Activity Relationship of Nitroxide Free Radicals and Their Precursors as Modifiers Against Oxidative Damage. Journal of Medicinal Chemistry 41:18, pages 3477-3492.
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Thomas M. Flicker & Sarah A. Green. (1998) Detection and Separation of Gas-Phase Carbon-Centered Radicals from Cigarette Smoke and Diesel Exhaust. Analytical Chemistry 70:9, pages 2008-2012.
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Tamás Kálai, Éva Hideg, Imre Vass & Kálmán Hideg. (1998) Double (Fluorescent and Spin) Sensors for Detection of Reactive Oxygen Species in the Thylakoid Membrane. Free Radical Biology and Medicine 24:4, pages 649-652.
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Carl G. Johnson, Sigalit Caron & Neil V. Blough. (1996) Combined Liquid Chromatography/Mass Spectrometry of the Radical Adducts of a Fluorescamine-Derivatized Nitroxide. Analytical Chemistry 68:5, pages 867-872.
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Neil V. Blough & Richard G. Zepp. 1996. Active Oxygen in Chemistry. Active Oxygen in Chemistry 280 333 .
John G. Dorsey, Joe P. Foley, William T. Cooper, Robert A. Barford & Howard G. Barth. (2002) Liquid chromatography: theory and methodology. Analytical Chemistry 64:12, pages 353-389.
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Timothy J. Bahowick, Veeravagu. Murugaiah, Andrew W. Sulya, Daniel B. Taylor & Robert E. Synovec. (2002) Column liquid chromatography: equipment and instrumentation. Analytical Chemistry 64:12, pages 255-270.
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Oliver C. Zafiriou & Brian Dister. (1991) Photochemical free radical production rates: Gulf of Maine and Woods Hole-Miami transect. Journal of Geophysical Research 96:C3, pages 4939.
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Brian Palenik, Neil M. Price & François M.M. Morel. (1991) Potential effects of UV-B on the chemical environment of marine organisms: A review. Environmental Pollution 70:2, pages 117-130.
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Takashi. Hayashita, Mi Ja. Goo, Jong Chan. Lee, Jong Seung. Kim, Jan. Krzykawski & Richard A. Bartsch. (2002) Selective sorption of alkali-metal cations by carboxylic acid resins containing acyclic or cyclic polyether units. Analytical Chemistry 62:21, pages 2283-2287.
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David J. Kieber & Neil V. Blough. (2002) Determination of carbon-centered radicals in aqueous solution by liquid chromatography with fluorescence detection. Analytical Chemistry 62:21, pages 2275-2283.
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O.C Zafiriou, N.V Blough, E Micinski, B Dister, D Kieber & J Moffett. (1990) Molecular probe systems for reactive transients in natural waters. Marine Chemistry 30, pages 45-70.
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