Advanced search
Publication Cover
Free Radical Research Volume 23, 1995 - Issue 5
Submit an article Journal homepage
78
Views
36
CrossRef citations to date
0
Altmetric
Original Article

Reactions of Low Valent Transition Metal Complexes with Hydrogen Peroxide. Are they “Fenton-Like” or not? 4. The Case of Fe(II)L, L = Edta; Hedta and Tcma

Esther Luzzatto Contribution from the Nuclear Research Centre Negev, the R. Bloch Coal Research Center and the Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel and Anorganische Chemie I, Ruhr Universitat Bochum, D-4630, Bochum, Germany; R. Bloch Coal Research Center and Chemistry Department, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva, Israel
,
Haim Cohen Contribution from the Nuclear Research Centre Negev, the R. Bloch Coal Research Center and the Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel and Anorganische Chemie I, Ruhr Universitat Bochum, D-4630, Bochum, Germany; R. Bloch Coal Research Center and Chemistry Department, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva, Israel; Chemistry Department, NCRN, P.O. Box 9001, Beer-Sheva, Israel
,
Claudia Stockheim Chemistry Department, NCRN, P.O. Box 9001, Beer-Sheva, Israel; Anorganische Chemie I, Ruhr Universitat Bochum, D-4630, Bochum, Germany
,
Karl Wieghardt Contribution from the Nuclear Research Centre Negev, the R. Bloch Coal Research Center and the Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel and Anorganische Chemie I, Ruhr Universitat Bochum, D-4630, Bochum, Germany
&
Dan Meyerstein Contribution from the Nuclear Research Centre Negev, the R. Bloch Coal Research Center and the Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel and Anorganische Chemie I, Ruhr Universitat Bochum, D-4630, Bochum, Germany; R. Bloch Coal Research Center and Chemistry Department, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva, Israel
Pages 453-463 | Received 11 Sep 1994, Published online: 07 Jul 2009

Citations (36)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (3)

Guy Ben Hamu, Dror Shamir, Moshe Zohar & Ariela Burg. (2018) Acceleration of the corrosion reaction of magnesium by Fenton reagents. Journal of Coordination Chemistry 71:11-13, pages 1852-1862.
Read now
Ariela Burg, Ella Fastovesky, Dror Shamir, Haya Kornweitz & Dan Meyerstein. (2016) The reaction between the peroxide VO(η2-O2)(pyridine-2-carboxylate)·2H2O and FeIIaq is not a Fenton-like reaction. Journal of Coordination Chemistry 69:11-13, pages 1722-1729.
Read now
Manfred Saran, Christa Michel, Kurt Stettmaier & Wolf Bors. (2000) Arguments against the significance of the Fenton reaction contributing to signal pathways under in vivo conditions. Free Radical Research 33:5, pages 567-579.
Read now

Articles from other publishers (33)

Anna-Katharina Ückert, Sina Rütschlin, Simon Gutbier, Nathalie Christine Wörz, Mahfuzur R. Miah, Airton C. Martins, Isa Hauer, Anna-Katharina Holzer, Birthe Meyburg, Ann-Kathrin Mix, Christof Hauck, Michael Aschner, Thomas Böttcher & Marcel Leist. (2023) Identification of the bacterial metabolite aerugine as potential trigger of human dopaminergic neurodegeneration. Environment International 180, pages 108229.
Crossref
Dan Meyerstein. (2022) What Are the Oxidizing Intermediates in the Fenton and Fenton-like Reactions? A Perspective. Antioxidants 11:7, pages 1368.
Crossref
Dan Meyerstein. (2021) Re-examining Fenton and Fenton-like reactions. Nature Reviews Chemistry 5:9, pages 595-597.
Crossref
Bartosz Skalski, Bogdan Kontek, Bernadetta Lis, Beata Olas, Łukasz Grabarczyk, Anna Stochmal & Jerzy Żuchowski. (2019) Biological properties of Elaeagnus rhamnoides (L.) A. Nelson twig and leaf extracts. BMC Complementary and Alternative Medicine 19:1.
Crossref
Beata Olas, Jerzy Żuchowski, Bernadetta Lis, Bartosz Skalski, Bogdan Kontek, Łukasz Grabarczyk & Anna Stochmal. (2018) Comparative chemical composition, antioxidant and anticoagulant properties of phenolic fraction (a rich in non-acylated and acylated flavonoids and non-polar compounds) and non-polar fraction from Elaeagnus rhamnoides (L.) A. Nelson fruits. Food Chemistry 247, pages 39-45.
Crossref
Weronika Adach & Beata Olas. (2017) The role of CORM-2 as a modulator of oxidative stress and hemostatic parameters of human plasma in vitro. PLOS ONE 12:9, pages e0184787.
Crossref
Dariusz Jędrejek, Bogdan Kontek, Bernadetta Lis, Anna Stochmal & Beata Olas. (2017) Evaluation of antioxidant activity of phenolic fractions from the leaves and petals of dandelion in human plasma treated with H2O2 and H2O2/Fe. Chemico-Biological Interactions 262, pages 29-37.
Crossref
Christopher J. Miller, Andrew L. Rose & T. David Waite. (2016) Importance of Iron Complexation for Fenton-Mediated Hydroxyl Radical Production at Circumneutral pH. Frontiers in Marine Science 3.
Crossref
J. Guadalupe Hernandez, Antonio Romero Silva, Pandiyan Thangarasu, Rafael Herrera Najera, Alfonso Duran Moreno, M. Teresa Orta Ledesma, Julian Cruz-Borbolla & Narinder Singh. (2015) Theoretical and experimental studies of phenol oxidation by ruthenium complex with N,N,N-tris(benzimidazol-2yl-methyl)amine. Journal of Molecular Modeling 21:9.
Crossref
Lars R. Bennedsen. 2014. Chemistry of Advanced Environmental Purification Processes of Water. Chemistry of Advanced Environmental Purification Processes of Water 13 74 .
Frank L. Y. Lam & Xijun Hu. (2013) pH-Insensitive Bimetallic Catalyst for the Abatement of Dye Pollutants by Photo-Fenton Oxidation. Industrial & Engineering Chemistry Research 52:20, pages 6639-6646.
Crossref
Sandra Rachmilovich-Calis, Alexandra Masarwa, Naomi Meyerstein, Dan Meyerstein & Rudi van Eldik. (2009) New Mechanistic Aspects of the Fenton Reaction. Chemistry - A European Journal 15:33, pages 8303-8309.
Crossref
Jing Fan, Xiaojing Shao, Haizhu Xu & Suling Feng. (2009) A novel inhibitory kinetic fluorimetric method for the determination of trace methomyl in environmental samples. Luminescence 24:4, pages 266-270.
Crossref
Frank L.Y. Lam & Xijun Hu. (2007) A high performance bimetallic catalyst for photo-Fenton oxidation of Orange II over a wide pH range. Catalysis Communications 8:12, pages 2125-2129.
Crossref
Huiqin Guo, Jing Fan & Yanhui Guo. (2007) A fluorimetric method for the determination of trace pentachlorophenol, based on its inhibitory effect on the redox reaction between the improved Fenton reagent and rhodamine B. Luminescence 22:5, pages 407-414.
Crossref
Frank L. Y. Lam, Alex C. K. Yip & Xijun Hu. (2007) Copper/MCM-41 as a Highly Stable and pH-insensitive Heterogeneous Photo-Fenton-like Catalytic Material for the Abatement of Organic Wastewater. Industrial & Engineering Chemistry Research 46:10, pages 3328-3333.
Crossref
Jing Fan, Hui-Qin Guo & Su-Ling Feng. (2007) Spectrofluorimetric Determination of Pentachlorophenol Based on Its Inhibitory Effect on The Redox Reaction Between Hydroxyl Radicals and Fluorescent Dye Rhodamine B. Journal of Fluorescence 17:3, pages 257-264.
Crossref
Zhiyong Cheng & Yuanzong Li. (2007) What Is Responsible for the Initiating Chemistry of Iron-Mediated Lipid Peroxidation:  An Update. Chemical Reviews 107:3, pages 748-766.
Crossref
Sandra Rachmilovich‐Calis, Alexandra Masarwa, Naomi Meyerstein & Dan Meyerstein. (2005) The Fenton Reaction in Aerated Aqueous Solutions Revisited. European Journal of Inorganic Chemistry 2005:14, pages 2875-2880.
Crossref
Richard J. WattsAmy L. Teel. (2005) Chemistry of Modified Fenton’s Reagent (Catalyzed H2O2 Propagations–CHP) for In Situ Soil and Groundwater Remediation. Journal of Environmental Engineering 131:4, pages 612-622.
Crossref
Yumin Chen & Ann E. Hagerman. (2004) Quantitative Examination of Oxidized Polyphenol−Protein Complexes. Journal of Agricultural and Food Chemistry 52:20, pages 6061-6067.
Crossref
ALEXANDRA MASARWA & DAN MEYERSTEIN. 2004. Including Bioinorganic Studies. Including Bioinorganic Studies 271 313 .
Stephan J. Hug & Olivier Leupin. (2003) Iron-Catalyzed Oxidation of Arsenic(III) by Oxygen and by Hydrogen Peroxide:  pH-Dependent Formation of Oxidants in the Fenton Reaction. Environmental Science & Technology 37:12, pages 2734-2742.
Crossref
Jolanta Głębska, Agnieszka Grzelak, Łukasz Pułaski & Grzegorz Bartosz. (2002) EDTA loses its antioxidant properties upon storage in buffer. Analytical Biochemistry 311:1, pages 87-89.
Crossref
Wojciech Szczepanik, Piotr Kaczmarek, Jarosław Sobczak, Wojciech Bal, Kazimierz Gatner & Małgorzata Jeżowska-Bojczuk. (2002) Copper( ii ) binding by kanamycin A and hydrogen peroxide activation by resulting complexes . New J. Chem. 26:10, pages 1507-1514.
Crossref
Antonio Rescigno & Enrico Sanjust. 2002. Bioactive Natural Products. Bioactive Natural Products 965 1028 .
K. Sigler, J. Chaloupka, J. Brozmanová, N. Stadler & M. Höfer. (1999) Oxidative stress in microorganisms—I. Folia Microbiologica 44:6, pages 587-624.
Crossref
Sara Goldstein & Dan Meyerstein. (1999) Comments on the Mechanism of the “Fenton-Like” Reaction. Accounts of Chemical Research 32:7, pages 547-550.
Crossref
Frank Neese & Edward I. Solomon. (1998) Detailed Spectroscopic and Theoretical Studies on [Fe(EDTA)(O 2 )] 3 - :  Electronic Structure of the Side-on Ferric−Peroxide Bond and Its Relevance to Reactivity . Journal of the American Chemical Society 120:49, pages 12829-12848.
Crossref
Antonio Rescigno, Andrea C. Rinaldi & Enrico Sanjust. (1998) Some aspects of tyrosine secondary metabolism. Biochemical Pharmacology 56:9, pages 1089-1096.
Crossref
Stefan H. Bossmann, Esther Oliveros, Sabine Göb, Silvia Siegwart, Elizabeth P. Dahlen, Leon Payawan, Matthias Straub, Michael Wörner & André M. Braun. (1998) New Evidence against Hydroxyl Radicals as Reactive Intermediates in the Thermal and Photochemically Enhanced Fenton Reactions. The Journal of Physical Chemistry A 102:28, pages 5542-5550.
Crossref
N. Winterton. (1997) Chapter 27. Inorganic mechanisms. Annual Reports Section "A" (Inorganic Chemistry) 93, pages 541.
Crossref
Christian Schöneich & Jian Yang. (1996) Oxidation of methionine peptides by Fenton systems: the importance of peptide sequence, neighbouring groups and EDTA. J. Chem. Soc., Perkin Trans. 2:5, pages 915-924.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.