Thermodynamic excess properties of binary mixtures of methanol + pyridine, methanol + benzene, and pyridine + benzene at several temperatures and atmospheric pressure

ABSTRACT

This work reports experimental densities and sound speeds at (293.15, 298.15, 303.15, 308.15, and 313.15) K and viscosities at 298.15 K for the binary liquid mixtures methanol + pyridine, methanol + benzene, and pyridine + benzene over the entire range of compositions and atmospheric pressure. The excess properties, namely the excess molar volume $V_m^E$, excess isentropic compressibility ${\kappa }_S^E$, and excess Gibbs energy for activation of viscous flow G*^E were calculated from experimental data and are fitted to Redlich-Kister polynomials. The results obtained were discussed in terms of molecular interactions between the mixing components and structural effects.

KEYWORDS:

• Thermodynamic excess properties
• alkanols
• pyridine
• benzene

Disclosure statement

No potential conflict of interest was reported by the authors.

Supplementary material

Supplemental data for this article can be accessed online at https://doi.org/10.1080/00319104.2023.2188213