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Journal of Coordination Chemistry Volume 72, 2019 - Issue 11
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Original Articles

Halogen bonding-assisted formation of one-dimensional polybromide–bromotellurate (2-ClPyH)2{[TeBr6](Br2)}

Andrey N. Usoltseva Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia; View further author information
,
Sergey A. Adonina Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia; ;b Novosibirsk State University, Novosibirsk, Russia; Correspondence[email protected]
View further author information
,
Alexander S. Novikovc Institute of Chemistry, Saint Petersburg State University, Saint Petersburg, Russia; View further author information
,
Maxim N. Sokolova Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia; ;b Novosibirsk State University, Novosibirsk, Russia; ;d Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, RussiaView further author information
&
Vladimir P. Fedina Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia; ;b Novosibirsk State University, Novosibirsk, Russia; View further author information
Pages 1890-1898 | Received 13 Jan 2019, Accepted 08 Apr 2019, Published online: 14 Jun 2019
 
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Abstract

Supramolecular hybrid (2-ClPy)2{[TeBr6](Br2)} (1) was prepared by the reaction of TeO2, Br2 and 2-chloropyridinium in HBr. In the structure, mononuclear [TeBr6]2− units are connected by {Br2} linkers into 1D zigzag-shaped infinite chains. Energies of halogen bonding were estimated by theoretical methods (1.3–3.3 kcal/mol).

Graphical Abstract

Additional information

Funding

This work was supported by Russian Science Foundation (Grant No. 18-73-10040).

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