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Journal of Coordination Chemistry Volume 74, 2021 - Issue 4-6
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Research Article

Luminescent sensing for amino acids with a Cd-MOF based on 4'-(1H-tetrazol-5-yl)-biphenyl-4-carboxylic acid

Ling Qina School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaCorrespondence[email protected]
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Qi-Ming Zhenga School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Hao Shena School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Peng-Cheng Zenga School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Huan-Jun Zhua School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Xi Yanga School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Yan-Qing Wanga School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Yong-Liang Zhanga School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, P. R. ChinaView further author information
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Ming-Dao Zhangb School of Environmental Science and Engineering, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science & Technology, Nanjing, 210044, P. R. ChinaView further author information
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Pages 630-636 | Received 23 Jun 2020, Accepted 30 Nov 2020, Published online: 09 Feb 2021
 
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Abstract

One luminescent Cd2+ coordination polymer, {[Cd(tbca)(H2O)]}n (1) (Htbca = 4'-(1H-tetrazol-5-yl)-biphenyl-4-carboxylic acid), has been synthesized and characterized by infrared spectroscopy and powder X-ray diffraction. Structural analysis revealed that 1 was a 3D framework with a 3,6-connected rtl topology. Fluorescence titration experiments demonstrated that 1 was an excellent multi-functional probe for metal ions and amino acids.

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Funding

This work was supported by grants from the National Natural Science Foundation of China (no. 21601045), China Postdoctoral Science Foundation (2016M601768), the Fundamental Research Funds for the Central Universities (JZ2019HGTB0059, 202010359097, X202010359591), A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), Jiangsu Joint Laboratory of Atmospheric Pollution Control, and Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials.

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