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Separation Science and Technology Volume 56, 2021 - Issue 1
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Adsorption

A porous anionic Co(II)-based MOF for selective gas sorption and treatment effect in acute glomerulonephritis via reducing inflammatory response

Gang Yea Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, ChinaCorrespondence[email protected]
,
Li Chena Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
Xiao-Xue Yina Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
De-Lin Liua Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
Min-Na Wanga Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
Qi-Feng Zhanga Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
Yuan Liua Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
,
Wei Liua Department of Emergency Intensive Care Unit, Beijing Luhe Hospital, Capital Medical University, Beijing, China
&
Heng-Yuan Zhangb Department of Nephropathy, Xiamen University, Xiamen, Fujian, China
 show all
Pages 36-44 | Received 20 Aug 2019, Accepted 20 Nov 2019, Published online: 01 Jan 2020
 
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ABSTRACT

A new MOF {(Me2NH2)[Co3(OH)2(TCPP)2(bpy)](DMF)15}n (1) was synthesized via the reaction of 4,4′-bipyridine and tetracarboxylic 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine (H4TCPP) binary ligands with Co(NO3)2 · 6H2O under the solvothermal conditions. Gas adsorption studies reveal that the mixtures of C2H2/CH4 and C2H2/CO2 could be selectively separated by the obtained activated 1a (solvent-free 1). The relative expression of tnf-α, nf-κb in the glomerular cells was measured by RT-PCR. The content of the IL-1β and IL-18 released by glomerular cells was determined by ELISA assay. The results obtained through molecular docking exhibited possible regulation mechanism on regulation of binding affinity between DNA and target protein.

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