The influence of temperature and cyclic loading on adhesion in polycarbonate-polyurethane-glass adhesive joint

Abstract

The paper deals with the influence of temperature and cyclic loading on adhesion and transparency of the adhesive joint consisting of soda-lime-silica glass and polycarbonate (PC) bonded with polyurethane (PU) adhesive film. The tested joint represents critical part of transparent armored glass used in vehicles. Dynamic tension creep tests were performed at temperatures to which armored glass is commonly exposed (25, 50, 60, 70, and 80 °C). Sawtooth loading mode was performed to 650 N and the sine loading in the force range 0–1550 N. The aim of the paper was to discover conditions causing delamination of the adhesive joint and glass milky appearance during the use. Delamination of soda-lime-silica glass/PU adhesive interface occurred at 25 °C after load to 1550 N without the change of transparency. Both dynamic and static tension creep tests performed to 400 N led to plastic deformation of PU adhesive at and above 70 °C, in preference at both ends and circumference edges of adhesive joint, and thus, to loss of transparency, but extent of deformation differed. Milky maps observed after sawtooth load to 650 N at 80 °C reflected delaminated areas of highly deformed PU adhesive. Temperature of 70 °C was found out to be the critical parameter being in synergy effect with different thermal expansion of PC and PU adhesive.

Keywords:

• Adhesive joint
• glass
• polycarbonate
• polyurethane
• temperature
• static and dynamic tension creep test

Additional information

Funding

The work was supported by the Ministry of Education Youth and Sports of the Czech Republic under the project FCH-S-18-5448 and SV17-FVL-K109-BIN, and by Ministry of Defence of the Czech Republic under the project OFVVU20140001.