Mechanism of As(V) adsorption from aqueous solution by chitosan-modified diatomite adsorbent

Abstract

Arsenic poses severe threats to human and ecosystem health. Various methods for arsenic removal, including the use of different adsorbents, have been employed. Herein, an adsorbent using refined diatomite as the matrix and chitosan as the modifying agent was evaluated. For effective design of adsorption systems, the structural changes during adsorbent modification and the adsorption process were investigated. The adsorbent was analyzed and characterized using scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), x-ray diffraction (XRD), and x-ray photoelectron spectroscopy (XPS). The feasibility of using chitosan-modified diatomite was explored by utilizing the batch equilibrium technique with varying experimental parameters, including the adsorbent dose, initial concentration of As(V), temperature, pH, and time. Additionally, chitosan-modified diatomite adsorption isotherms and adsorption kinetics were studied. The ability of the adsorbent to remove As(V) from an aqueous solution before and after modification was investigated via a static adsorption experiment. No change was found in the diatomite matrix after modification; however, the adsorption peaks of the functional groups changed. The organic phase peak revealed by XRD disappeared, whereas a nitrogen phase peak appeared. During modification, open chains of chitosan were grafted effectively onto the diatomite surface. Chitosan-modified diatomite can be used to coordinate an adsorption reaction with arsenate through surface –NH₂. The optimum conditions for adsorption at an initial As(V) concentration of 2 mg/L were a pH of 5, temperature of 25 °C, reaction time of 60 min, and an adsorbent dose of 3 g/L. Chitosan-modified diatomite can remove As(V) from aqueous solutions significantly better than unmodified diatomite.

Graphical Abstract

Keywords:

• Arsenic
• adsorption
• chitosan-modified diatomite
• mechanism

Disclosure statement

There are no conflicts of interest to declare.

Additional information

Funding

This work was supported by the National Natural Science Foundation of China under Grant Numbers 41662005 and 51564008; the Natural Science Foundation of Guangxi Province under Grant Number 2019GXNSFBA245083; the Guangxi Science and Technology Project under Grant Number 14124004-5-5; the Project of High-Level Innovation Team and Outstanding Scholar in Guangxi Colleges and Universities under Grant Number 002401013001; and the Guangxi Scientific Experiment Center of Mining, Metallurgy and Environment under Grant Number KH2012ZD004.