Investigation of the viscoelastic properties of 4-propoxy-biphenyl-4-carbonitrile

ABSTRACT

We report on the temperature-dependent measurements of dielectric permittivity, birefringence, elastic constants and rotational viscosity for 4-propoxy-biphenyl-4-carbonitrile in the nematic region. The temperature dependence of the three elastic constants was determined from studies of the Freédericksz transition. The thermal dependence of elastic constants shows features similar to the literature (bend > splay > twist). Elastic constants are proportional to the square of the order parameter. Temperature-dependent dielectric characterisation was carried out at a frequency of 10 kHz. The compound shows positive dielectric anisotropy in the nematic phase. The rotational viscosity is found to be relatively low. Temperature dependence of order parameter is estimated using Haller’s method. The figure of merit was also calculated as a function of temperature.

Graphical abstract

KEYWORDS:

• Liquid crystal
• dielectric permittivity
• birefringence
• elastic constant
• rotational viscosity
• figure of merit

Disclosure statement

No potential conflict of interest was reported by the authors.