Chitosan/glyphosate formulation as a potential, environmental friendly herbicide with prolonged activity

Abstract

Although there are many reports on the dangers posed by glyphosate, this herbicide is still one of the most popular and widely used total weed killers. Therefore, great effort should be made to minimize exposure to this herbicide and limit its losses into the environment. The aim of this study was to prepare a new formulation consisted of various molecular weight chitosans with glyphosate and their evaluation toward active substance release, phytotoxicity, and preliminary herbicidal efficiency. The phytotoxicity study of the obtained chitosan/glyphosate formulations was determined based on the Organisation for Economic Co-operation and Development 208 guideline. Among all tested formulations evaluated for phytotoxicity, that containing the highest molecular weight of chitosan was found to be the least toxic, showing simultaneously the most effective herbicidal activity against selected weeds. The release rate of glyphosate from the obtained formulations was dependent on the molecular weight and viscosity of chitosan.

Keywords:

• Chitosan
• glyphosate
• N-phosphonomethyl glycine
• phytotoxicity
• herbicide
• pesticide delivery system

Acknowledgments

I would like to thank Professor Volodymyr Pavlyuk from Jan Długosz University in Czestochowa, Poland, for the discussion on XRD results.