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Journal of Energetic Materials Volume 42, 2024 - Issue 1
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Research Article

A novel ternary energetic compound: DAF/DNP/H2O cocrystal

Xiaopeng Zhanga School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, China;b School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaView further author information
,
Yige Wuc Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin, ChinaView further author information
,
Shaohua Jinb School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaView further author information
,
Guanchao Lanb School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaView further author information
,
Xiaojun Wangc Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin, ChinaView further author information
,
Junfeng Wangd State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, ChinaView further author information
,
Fenqing Shangc Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin, ChinaView further author information
,
Shusen Chenb School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaView further author information
,
Junyi Dub School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaCorrespondence[email protected]
View further author information
&
Qinghai Shub School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, ChinaCorrespondence[email protected]
View further author information
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Pages 84-96 | Published online: 20 Jan 2022
 
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ABSTRACT

A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

Acknowledgments

We also gratefully acknowledge the support of Ran Liu and Haijiao Xie in the Shiyanjia lab (www.shiyanjia.com).

Disclosure Statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the Fundamental Research Funds for the Central Universities.

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