Molecular dynamics simulations on aqueous solution confined in charged nanochannels: asymmetric effect of surface charge

ABSTRACT

This work aims at investigating the effect of surface charge sign on static and dynamic properties of aqueous solutions confined in the charged nanochannel. Molecular dynamics simulations of two confinement systems have been performed, in which the nanochannel walls were modelled as the structureless walls with the uniform continuous distribution of surface charge. It is found that the sign of surface charge has a noticeable impact on the aqueous solution in a region close to the wall. The aqueous solution is more strongly layered and less translational and rotational diffusive in the positively charged nanochannel. But, the water molecules are more preferably oriented in the negatively charged nanochannel. The results have been consistently explained by microscopically analysing the forces acting atoms of water molecules and counter-ions, and the contributions into the torque acting on the water molecule.

KEYWORDS:

• Aqueous solutions
• charged nanochannel
• surface effect
• structureless wall
• molecular dynamics simulations

Acknowledgements

The authors are grateful to Prof. Yong Kweon Suh of Dong A university and Prof. Hoai Nam Tran of Duy Tan university for their valuable discussions during the preparation of the manuscript. One of the authors, Ms Thi Ha Tran would like to thank the Domestic Master/ PhD Scholarship Programme of Vingroup Innovation Foundation for supporting tuition fee.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) [grant number 103.01-2019.49].