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Journal of Asian Natural Products Research Volume 21, 2019 - Issue 7
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Three new polyketides from Ascotricha sp. ZJ-M-5 by the OSMAC strategy

Ya-Jing DongKey Laboratory of Structure-Based Drug Design & Discovery (Shenyang Pharmaceutical University), Ministry of Education, Shenyang Pharmaceutical University, Shenyang110016, China;School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang110016, China
,
Guo-Mei HouKey Laboratory of Structure-Based Drug Design & Discovery (Shenyang Pharmaceutical University), Ministry of Education, Shenyang Pharmaceutical University, Shenyang110016, China;School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang110016, China
,
Bin LinSchool of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang110016, China
,
Dan-Yi LiSchool of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang110016, China
&
Zhan-Lin LiKey Laboratory of Structure-Based Drug Design & Discovery (Shenyang Pharmaceutical University), Ministry of Education, Shenyang Pharmaceutical University, Shenyang110016, China;School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang110016, ChinaCorrespondence[email protected]
ORCID Iconhttp://orcid.org/0000-0001-5306-3396
ORCID Icon
Pages 689-695 | Received 24 Jan 2018, Accepted 26 Apr 2018, Published online: 21 May 2018
 
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Abstract

Three new compounds, ascotrichols A-B (1–2) and ascotrichrone A (3), along with two known isocoumarin derivatives (4–5), were isolated from the solid culture of a sea mud-derived fungus, Ascotricha sp. ZJ-M-5 on rice media. The structures were elucidated by extensive spectroscopic analyses, including 1D and 2D NMR data, and the absolute configurations were determined by electronic circular dichroism and biogenetic correlation.

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