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Journal of Asian Natural Products Research Volume 21, 2019 - Issue 10
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Original Articles

Isoscoparins R and S, two new ent-clerodane diterpenoids from Isodon scoparius

Xing-Ren Li Key Laboratory of Medicinal Chemistry for Natural Resources, Ministry of Education, School of Chemical Science and Technology, Yunnan University , Kunming650091, China; State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Qiang Fu Department of Biomedical Sciences, City University of Hong Kong, Kowloon Tong , Hong Kong, China
,
Min Zhou State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Kun Hu State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Xue Du State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Xiao-Nian Li State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Han-Dong Sun State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, China
,
Jian-Bo Yue Department of Biomedical Sciences, City University of Hong Kong, Kowloon Tong , Hong Kong, China; Shenzhen Research Institute of City University of Hong Kong , Shenzhen518057, China
,
Hong-Bin Zhang Key Laboratory of Medicinal Chemistry for Natural Resources, Ministry of Education, School of Chemical Science and Technology, Yunnan University , Kunming650091, ChinaCorrespondence[email protected]
&
Pema-Tenzin Puno State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences , Kunming650201, ChinaCorrespondence[email protected]
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Pages 977-984 | Received 10 Mar 2018, Accepted 22 May 2018, Published online: 06 Jun 2018
 
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Abstract

Two new ent-clerodane diterpenoids, named isoscoparins R and S (1 and 2), were isolated from the aerial parts of Isodon scoparius. Their structures were characterized mainly by analyzing the NMR and HRESIMS data, and the relative configuration of compound 1 was determined by single-crystal X-ray diffraction. Compound 2 showed weak activity as an autophagic inhibitor.

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