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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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REVIEW

Stereochemistry of electrophilic and nucleophilic substitution at phosphorus

Oleg I. KolodiazhnyiInstitute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences, Kiev, UkraineCorrespondence[email protected]
Pages 396-400 | Received 15 Jul 2018, Accepted 31 Aug 2018, Published online: 26 Oct 2018
 
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Abstract

Stereochemistry and mechanisms of nucleophilic [SN2(P)] and electrophilic [SE2(P)} reactions have been analyzed, discussed and confirmed by experimental studies. SE2(P) reactions proceed with the retention of absolute configuration, while the SN2(P) reactions react with the inversion of the configuration at the phosphorus atom.

GRAPHICAL ABSTRACT

Disclosure statement

No potential conflict of interest was reported by the author.

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