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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

Novel 1,3,2-diazaphospholidines with pseudodipeptide substituents

I. V. ChuchelkinChemistry Department, Ryazan State University, Ryazan, Russian Federation; Correspondence[email protected]
ORCID Iconhttp://orcid.org/0000-0002-3656-468XView further author information
ORCID Icon,
V. K. GavrilovChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
I. D. FirsinChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
V. S. ZimarevChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
I. M. NovikovChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
M. G. MaksimovaChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
A. A. ShiryaevChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
S. V. ZheglovChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
,
V. A. TafeenkoDepartment of Chemistry, Lomonosov Moscow State University, Leninskie Gory, GSP-1, Moscow, 119991, Russian FederationView further author information
,
V. V. ChernyshevDepartment of Chemistry, Lomonosov Moscow State University, Leninskie Gory, GSP-1, Moscow, 119991, Russian FederationView further author information
&
K. N. GavrilovChemistry Department, Ryazan State University, Ryazan, Russian Federation; View further author information
 show all
Pages 493-496 | Received 13 Sep 2018, Accepted 03 Oct 2018, Published online: 30 Dec 2018
 
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Abstract

Chiral 1,3,2-diazaphospholidine with pseudodipeptide substituents was prepared. This asymmetric inducer provided up to 84% ee in the Pd-catalyzed asymmetric allylic alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate, and up to 53% ee in the Rh-catalyzed asymmetric hydrogenation of (Z)-methyl 2-acetamido-3-phenylacrylate.

Graphical Abstract

Additional information

Funding

This work was financially supported by the Russian Science Foundation (Grant № 17-73-10356).

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