Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
Submit an article Journal homepage
212
Views
3
CrossRef citations to date
0
Altmetric
Short Communication

Microwave-assisted synthesis of phosphonic and phosphinic esters and phosphine oxides by the Hirao reaction

Réka HenyeczDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryCorrespondence[email protected]
View further author information
Pages 372-376 | Received 10 Oct 2018, Accepted 02 Nov 2018, Published online: 05 Mar 2019
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Phosphinic- and phosphonic esters, as well as phosphine oxides can be easily obtained by P–C coupling reactions of aryl- and vinyl halides with dialkyl phosphites, H-phosphinates and secondary phosphine oxides in the presence of mostly Pd catalysts. The use of the microwave (MW) technique allows the realization of the Hirao reaction more efficiently, economically and environmentally-friendly.

Acknowledgement

This project was supported through the New National Excellence Program of the Ministry of Human Capacities (ÚNKP-18-3-I-BME-118). R.H. is grateful to G. Keglevich for his collaboration.

Additional information

Funding

This project was supported through the New National Excellence Program of the Ministry of Human Capacities (ÚNKP-18-3-I-BME-118). R.H. is grateful to G. Keglevich for his collaboration.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 2,235.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.