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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Short Communication

Synthesis of organophosphates starting from α-hydroxyphosphonates

Nóra Z. Kiss Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary; Correspondence[email protected]
,
Zita Rádai Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary;
,
Réka Szabó Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary;
,
Youness Aichi Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco
,
Laila Laasri Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco
&
Said Sebti Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco
Pages 370-371 | Received 29 Sep 2018, Accepted 09 Nov 2018, Published online: 11 Dec 2018
 
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Abstract

α-Hydroxyphosphonates were successfully converted to the corresponding phosphates applying the phospha-Brook rearrangement under phase transfer catalytic conditions. Among several possible catalysts tested, K2CO3, Cs2CO3, as well as modified Moroccan phosphates were found to be suitable.

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