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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Short Communication

Rational synthesis of α-hydroxyphosphonic derivatives including dronic acids

Alajos GrünDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary; Correspondence[email protected]
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,
Zita RádaiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary; View further author information
,
Dávid Illés Sőregi-NagyDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary; View further author information
,
István GreinerGedeon Richter Plc, Budapest, HungaryView further author information
&
György KeglevichDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary; View further author information
Pages 386-387 | Received 28 Sep 2018, Accepted 30 Nov 2018, Published online: 09 Jan 2019
 
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Abstract

New, green methods have been elaborated for the syntheses of α-hydroxyphosphonates and α-hydroxymethylenebisphosphonic derivatives (HMBPs, dronates). α-Hydroxyphosphonates were prepared via the Pudovik reaction, while the synthesis of HMBPs has been performed in the three-component reaction of carboxylic acids, phosphorus trichloride and phosphorus acid.

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Funding

The above project was supported by the National Research Development and Innovation Fund (K119202). Z. Rádai is grateful for the fellowship provided by Chinoin–Sanofi Pharmaceuticals and József Varga Foundation. Z. Rádai was supported by the ÚNKP-18-3-IV-BME-265 New National Excellence Program of the Ministry of Human Capacities.

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