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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 196, 2021 - Issue 1
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Research Article

Trichloroisocyanuric acid-promoted thiolation of phosphites by thiols

Yingying ChenCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou, ChinaView further author information
,
Meichao LiCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou, ChinaView further author information
,
Zhangshui GongR & D Department, Hangzhou Toka Ink Co. Ltd., Hangzhou Economic & Technological Development Area, Hangzhou, ChinaView further author information
&
Zhenlu ShenCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou, ChinaCorrespondence[email protected]
View further author information
Pages 19-27 | Received 04 May 2020, Accepted 19 Jul 2020, Published online: 03 Aug 2020
 
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Abstract

A simple and convenient method for the synthesis of thiophosphates by coupling of phosphites with thiols under mild conditions has been developed. The reactions were promoted by trichloroisocyanuric acid (TCCA) and were carried out at room temperature in a one-pot two-step procedure within 20 min. A variety of substrates was tolerated in this method. Notably, both aryl and alkyl thiols could afford the corresponding thiophosphates in good yields.

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Additional information

Funding

This work was financially supported by the National Natural Science Foundation of China (21776260 and 21773211).

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