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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 195, 2020 - Issue 11: PBSI-2019 special issue
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Articles

The influence of varying reaction conditions on the coordination behavior of the phosphonoformate anion

M. EgenhöferDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany; Correspondence[email protected]
,
S. BarileDipartimento di Farmacia–Scienze del Farmaco, Università degli Studi di Bari “Aldo Moro”, Bari, Italy
,
V. CapriatiDipartimento di Farmacia–Scienze del Farmaco, Università degli Studi di Bari “Aldo Moro”, Bari, Italy
&
K. KaraghiosoffDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany; Correspondence[email protected]
Pages 949-951 | Published online: 25 Sep 2020
 
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Abstract

In medical and pharmaceutical science phosphonic acids and phosphonates play an important role with regard to their wide application in various drugs as medicines against osteoporosis or antiviral agents. In the course of the investigations on the coordination chemistry of biologically active phosphonates different salts of the phosphonoformate anion were prepared via hydrolysis of corresponding esters under basic conditions. Depending on the reaction and crystallization conditions, different sodium salts with the phosphonoformate moiety were obtained and structurally characterized.

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