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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Articles

Silica gels grafting with upper rim tetraphosphorylated tetrahydroxy(thia)calixarenes. Europium(III) sorption

Yuriy Boikoa Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine;b National University of Kyiv-Mohyla Academy, Kyiv, UkraineORCID Iconhttps://orcid.org/0000-0003-4767-8778View further author information
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Konstantin Belikovc State Scientific Institution “Institute for Single Crystals,” NAS of Ukraine, Kharkiv, Ukraine;d V.N.Karazin, Kharkiv National University, Kharkiv, UkraineORCID Iconhttps://orcid.org/0000-0002-1682-6064View further author information
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Ekaterina Brylevac State Scientific Institution “Institute for Single Crystals,” NAS of Ukraine, Kharkiv, UkraineORCID Iconhttps://orcid.org/0000-0002-8903-4922View further author information
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Zinaida Buninac State Scientific Institution “Institute for Single Crystals,” NAS of Ukraine, Kharkiv, UkraineORCID Iconhttps://orcid.org/0000-0002-8639-958XView further author information
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Victoria Varchenkoc State Scientific Institution “Institute for Single Crystals,” NAS of Ukraine, Kharkiv, UkraineORCID Iconhttps://orcid.org/0000-0002-7369-1637View further author information
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Andriy Drapailoa Institute of Organic Chemistry, NAS of Ukraine, Kyiv, UkraineORCID Iconhttps://orcid.org/0000-0002-8701-1380View further author information
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Roman Rodika Institute of Organic Chemistry, NAS of Ukraine, Kyiv, UkraineORCID Iconhttps://orcid.org/0000-0003-2258-6957View further author information
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Alexander Golubb National University of Kyiv-Mohyla Academy, Kyiv, UkraineORCID Iconhttps://orcid.org/0000-0003-1823-2523View further author information
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Alexander Katze Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA, USAView further author information
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Vitaly Kalchenkoa Institute of Organic Chemistry, NAS of Ukraine, Kyiv, UkraineCorrespondence[email protected]
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Pages 579-582 | Received 23 Nov 2021, Accepted 22 Dec 2021, Published online: 06 Jan 2022
 
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Abstract

Sequential treatment of silica gel with tetrachlorosilane and cone-shaped tetraphosphorylated tetrahydroxy(thia)calixarenes yielded porous organo-inorganic sorbents, the surface of which is covered by spatially ordered phosphonate, phosphinate and phosphine oxide groups capable of co-operative binding of metal cations. Sorption of europium(III) by the modified silica gels was studied.

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Funding

This work was partially supported by the National Academy of Sciences of Ukraine through grant «Synthesis of selective ligands and surface modification of polymeric materials for radionuclide extraction».

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