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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Short Communications

Generation of tert-butyl-λ5-phosphanedione and its chemical properties

Oleg KolodiazhnyiNAS of Ukraine, Kukhar’ Institute of Bioorganic Chemistry and Petrochemistry, Kyiv, UkraineCorrespondence[email protected]
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,
Olga KolodiazhnaNAS of Ukraine, Kukhar’ Institute of Bioorganic Chemistry and Petrochemistry, Kyiv, UkraineView further author information
,
Evgen GrishkunNAS of Ukraine, Kukhar’ Institute of Bioorganic Chemistry and Petrochemistry, Kyiv, UkraineView further author information
,
Anastasy KolodiazhnaNAS of Ukraine, Kukhar’ Institute of Bioorganic Chemistry and Petrochemistry, Kyiv, UkraineView further author information
&
Sergei SheikoNAS of Ukraine, Kukhar’ Institute of Bioorganic Chemistry and Petrochemistry, Kyiv, UkraineView further author information
Pages 657-659 | Received 20 Dec 2021, Accepted 13 Jan 2022, Published online: 01 Feb 2022
 
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Abstract

Tert-butyl-λ5-phosphanedione was generated by flash vacuum thermolysis (FVT) of trimethylsilyl tert-butyl phosphonohalidates. The structure of tert-butyl-λ5-phosphanedione was confirmed by chemical reactions. Tert-butyl-λ5-phosphandione readily undergoes trimerization, enters into the [2 + 3] - cycloaddition reaction with 2-phenyloxirane and adds alcohols.

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Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

National Academy of Sciences of Ukraine.

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