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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 8
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Review

Recent advances in the chemistry of chlorosulfonyl isocyanate: a review

Yasmine Chemama Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, AlgeriaCorrespondence[email protected]
,
Zineb Aoufa Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, Algeria
,
Aϊcha Amiraa Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, Algeria;b National Higher School of Mining and Metallurgy Amar Laskri Annaba, Annaba, Algeria
,
Hacene K’tira Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, Algeria
,
Houria Bentoumia Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, Algeria
,
Racha Ghodbanea Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, Algeria
,
Rachida Zerroukic Laboratory of Natural Substances Chemistry, Faculty of Sciences and Technologies, Limoges Cedex, France
&
Nour-Eddine Aoufa Bioorganic Chemistry Group, Laboratory of Applied Organic Chemistry, Department of Chemistry, Faculty of Sciences, Badji Mokhtar University, Annaba, AlgeriaORCID Iconhttps://orcid.org/0000-0003-1400-8444
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Pages 777-787 | Received 08 Feb 2022, Accepted 18 Mar 2022, Published online: 11 Apr 2022
 
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Abstract

This review article, containing 52 references, surveys recent achievements of the use of chlorosulfonyl isocyanate (CSI) in organic synthesis. In particular, the application for the preparation of several bioactive products containing the sulfamoyl moiety, which have been published in the last decade, is summarized.

CSI is a versatile reagent and displays excellent reactivity versus compounds with different functional groups such as amines, alcohols, olefins, carboxylic acids, thiols, epoxides etc. It is, thus, widely used as key intermediate for the insertion of the sulfamoyl moiety in various compounds.

Graphical Abstract

Acknowledgments

We gratefully acknowledge financial support from General Directorate for Scientific Research and Technological Development (DG-RSDT) and Algerian Ministry of Scientific Research.

Project PRFU Number: B00201UN2301120200006.

Conflict of interest

The authors declare that they have no conflict of interest.

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