Platinum concentration in PM_2.5 in the Mexico City Metropolitan Area: relationship to meteorological conditions

Abstract

Platinum (Pt) concentrations in PM_2.5 were evaluated by means of inductively coupled plasma mass spectrometry (ICP-MS) to evaluate the spatial and temporal behavior and to assess trends. Samples were taken from five representative sites in the Mexico City Metropolitan Area (MCMA): Tlalnepantla-northwest (NW), San Agustin-northeast (NE), La Merced -center (C), Coyoacan-southwest (SW), and Universidad Autonoma Metropolitana Iztapalapa-southeast (SE). Under three weather conditions: dry warm (DW-April), rainy (R-August), and dry cold (DC-November) in 2013. We found that the PM_2.5 median mass concentration was 24 μg m⁻³ ± 15 μg m⁻³ while Pt concentration was 55 pg m⁻³ ± 15 pg m⁻³ (median, interquartile range). Seasonal trend was identified: the concentrations decreased significantly in the following order DC > R>DW. No spatial distribution was observed. Interestingly, among other meteorically parameters, wind intensity resulted to be the major factor for the dispersion of Pt in PM2.5 in MCMA. Furthermore, we found that Pt concentrations increased significantly by 19.6% between 2011 and 2013. Regardless of the increase in Pt, carbon monoxide (CO) levels decreased opposite to a rise in vehicular fleet. These results urge for environment public policies that address the upward tendency of Pt levels especially in urban areas.

Keywords:

• platinum
• PM_2.5
• atmospheric pollution
• Mexico City Metropolitan Area
• meteorological conditions

Acknowledgements

Rodrigo Garza-Galindo gratefully acknowledges a grant from CONACyT (Consejo Nacional de Ciencia y Tecnología).