Iron nitride, α″-Fe₁₆N₂, around <100> interstitial type dislocation loops in neutron-irradiated iron

ABSTRACT

Atom probe tomography (APT) and selected area electron diffraction (SAED) by transmission electron microscopy (TEM) were applied to nano-scale precipitates formed in a neutron-irradiated iron (99.99% pure) at high temperatures. In the conventional TEM, we discovered donut-type precipitates on the {100} planes that formed at the dilatational side of interstitial type dislocation loops with the Burgers vector of <100> on the habit planes of {100} in the bcc iron lattice. The precipitates were identified as nitride, bct α″-Fe₁₆N₂, by chemical composition and lattice structural analyses using APT and SAED. Image contrasts of the α″-Fe₁₆N₂ in a weak beam dark-field electron microscopy study were carefully analysed with the diffraction vector and the sign of deviation parameter from the Bragg condition, and it was concluded to be a selective visualisation of α″-Fe₁₆N₂ on one of the {100} planes. These results were in agreement with the crystallographic orientation between the α″-Fe₁₆N₂ and matrix iron, thereby bridging a knowledge gap in α″-Fe₁₆N₂ formation during neutron irradiation using a sodium-cooled experimental fast reactor, JOYO, or a 14 MeV D-T neutron source, RTNS-II.

KEYWORDS:

• α″-Fe₁₆N₂
• neutron irradiated iron
• interstitial type dislocation loops
• nitride
• atom prove tomography

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