Abstract
We examine the hydrogen adsorption behavior of chabazite (CHA) and Linde Type A (LTA) zeolites, both of which possess an eight-membered ring (Si8O8), as the temperature was increased from 77 K (thermal adsorption spectroscopy). The CHA-type zeolites started to uptake hydrogen at around 200 K, whereas no other adsorbent showed any hydrogen uptake. The hydrogen adsorption temperature of CHA was similar to that observed by thermal desorption spectroscopy. A high D2/H2 separation ability at relatively high temperature in the CHA-type zeolites may be expected in the intrinsic adsorption property.
Acknowledgments
This work was supported by the Grants-in-Aid for Scientific Research (KAKENHI, 19H01872) and the NIFS Collaboration Research Program (NIFS22KIEA002).
Disclosure Statement
No potential conflict of interest was reported by the authors.