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Soft Materials Volume 20, 2022 - Issue sup1: Complex and Magnetic Soft Matter Systems. Guest editors: Yuriy Raikher, Maria Bălăşoiu, Octavian Mădălin Bunoiu, Norbert Kučerka, and Andrey Rogachev
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Research Article

Diamond-based nanostructures with metal-organic molecules

Vasily T. Lebedeva Neutron Research Department, Petersburg Nuclear Physics Institute named by B.P. Konstantinov, NRC “Kurchatov Institute”, Gatchina, Leningrad Distr, RussiaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0003-4894-0862View further author information
ORCID Icon,
Gyula Törökb Reactor Department, Atomic Energy Research Institute, MTA, KFKI, Budapest, HungaryView further author information
,
Yury V. Kulvelisa Neutron Research Department, Petersburg Nuclear Physics Institute named by B.P. Konstantinov, NRC “Kurchatov Institute”, Gatchina, Leningrad Distr, RussiaORCID Iconhttps://orcid.org/0000-0002-3228-3039View further author information
ORCID Icon,
Olga I. Bolshkovaa Neutron Research Department, Petersburg Nuclear Physics Institute named by B.P. Konstantinov, NRC “Kurchatov Institute”, Gatchina, Leningrad Distr, RussiaView further author information
,
Natalia P. Yevlampievac Physical Faculty, St. Petersburg State University, St. Petersburg, RussiaView further author information
,
Marina A. Sorokaa Neutron Research Department, Petersburg Nuclear Physics Institute named by B.P. Konstantinov, NRC “Kurchatov Institute”, Gatchina, Leningrad Distr, RussiaView further author information
,
Eduard V. Fomina Neutron Research Department, Petersburg Nuclear Physics Institute named by B.P. Konstantinov, NRC “Kurchatov Institute”, Gatchina, Leningrad Distr, RussiaView further author information
,
Alexander Ya Vuld Physical-Technical Institute named by A.F.Ioffe, Laboratory of Physics of Cluster Structures, St. Petersburg, RussiaView further author information
&
Seema Garge Department of Chemistry, Amity Institute of Applied Sciences, Amity University, Noida, Uttar Pradesh, IndiaORCID Iconhttps://orcid.org/0000-0002-0045-557XView further author information
ORCID Icon show all
Pages S34-S43 | Received 16 Jun 2021, Accepted 08 Oct 2021, Published online: 22 Oct 2021
 
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ABSTRACT

Recent results on synthesis, structural, and physicochemical studies of complexes based on detonation nanodiamonds modified with metal-organic molecules with functional magnetic and fluorescent properties have been presented. Neutron scattering experiments have discovered subtle features of the assembly of electro-negative molecules of Eu diphthalocyanines and nanodiamonds with positive surface potential in aqueous media. Nanoscale ordering of diamonds reinforced by their linking via diphthalocyanines was confirmed by TEM. The stable complexes possess X-ray luminescent and magnetic properties. Such nanostructures with low toxicity are prospective as contrasting and photoactive agents for magnetic resonance imaging and photodynamic therapy.

Acknowledgments

The work was supported by the Russian Foundation for Basic Researches under Grant no. 18-29-19008. The authors are grateful for TEM measurements carried out at the Interdisciplinary Resource Center for Nanotechnology, St. Petersburg State University Science Park.

Disclosure Statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the the Russian Foundation for Basic Research (RFBR) [18-29-19008].

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