Migration of mineral oil hydrocarbons from food contact papers into food simulants and extraction from their raw materials

ABSTRACT

To determine the occurrence of mineral oil hydrocarbons (MOH) in food contact papers in China, and to investigate the potential sources of MOH contamination, a total of 159 food contact papers and raw materials were analysed by off-line solid-phase extraction-gas chromatography flame ionisation detection (SPE-GC-FID) and a GC-MS method. The migration of MOH from food contact papers into Tenax, olive oil or 50% ethanol under the worst foreseeable conditions of use was determined. The results indicated that the occurrence of MOH in China is of a potential health risk concerning the migration of mineral oil saturated hydrocarbons (MOSH) and mineral oil aromatic hydrocarbons (MOAH) which were detected in 82.6% and 50.4% of samples, respectively. Migration of MOSH from 47.9% of samples was higher than 2 mg/kg and migration of MOAH from 32.2% samples exceeded 0.5 mg/kg in case of the worst foreseeable condition of use. The highest mean migration of MOSH and MOAH were found in packaging papers for long-term storage (more than 6 months), with mean migration of 91.2 mg/kg and 1.4 mg/kg, respectively. Migration of MOH from printed paper was considerably higher than that of unprinted paper, validating previous findings that the printing ink is the predominant source of MOH contamination in food contact papers. Migration of MOH from paper bowls used for packing instant noodles was relatively low, suggesting the internal hollow layer may be acting as a functional barrier that could block the transfer of MOH (up to C28) through the gas phrase, even though the outer layer was made from recycled paper. High concentrations of MOSH and MOAH were also detected in de-foamers, adhesives and rosin sizing agents, indicating that the MOH contamination caused by the use of raw materials and additives should also be taken into consideration.

KEYWORDS:

• Mineral oil saturated hydrocarbons (MOSH)
• mineral oil aromatic hydrocarbons (MOAH)
• food contact papers and paperboards
• migration
• raw materials and additives
• solid phase extraction-gas chromatography flame ionisation detector (SPE-GC-FID)

Acknowledgments

Financial support was provided by the National Key R&D Program of China (2016YFF0203705), the General Administration of Quality Supervision, the Inspection and Quarantine of the People’s Republic of China (2018GDK07, 2016IK057)  and  the Guangzhou Customs Disctrict (2020GZCK-010) are gratefully acknowledged.

Additional information

Funding

This work was supported by the General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China [2018GDK07, 2016IK057, 2014IK089]; Financial support from the National Key R&D Program of China [2016YFF0203705].