106
Views
0
CrossRef citations to date
0
Altmetric
Research Articles

Chemical stability investigation of haloolefin refrigerants and their blends with lubricants

Pages 936-953 | Received 08 Feb 2023, Accepted 26 Jul 2023, Published online: 27 Sep 2023
 

Abstract

This paper examines the findings of highly accelerated life tests (HALT), conducted according to ASHRAE Standard 97 sealed glass tube methodology for R-123 like, R-134a like and R-410A/R-404A like lower global warming potential (GWP) alternatives. Additionally, possible chemical breakdown pathways are reviewed for the new haloolefin refrigerants. Note, compositions for the following blends are shown as percent by weight. For R-123 like refrigerants, R-1336mzz(Z), R-1336mzz(E), R-514A (74.7% R-1336mzz(Z)/25.3% R-1130(E)), R-1233zd(E), and R-1224yd(Z) were examined with and without lubricants. R-1233zd(E) and R-1224yd(Z) were evaluated with mineral oil and the rest were evaluated with polyalkylene glycol (PAG), polyolester (POE) and polyvinyl ether (PVE) lubricants. For R-134a like refrigerants, R-1234ze(E), R-450A (42% R-134a/58% R-1234ze(E)), R-515B (91.1% R-1234ze(E)/8.9% R-227ea), R-1234yf, R-513A (56% R-1234yf/44% R-134a), and R-516A (77.5% R-1234yf/8.5% R-134a/14.0% R-152a) were examined with and without PAG, POE, and PVE lubricants. For R-410A/R-404A like, R-454B (68.9% R-32/31.1% R-1234yf), R-454C (21.5% R-32/78.5% R-1234yf), R-455A (3.0% R-744/21.5% R-32/75.5% R-1234yf), and R-468A (3.5% R-1132a/21.5% R-32/75.0% R-1234yf) were also examined with PAG, POE and PVE lubricants. R-466A (49% R-32/11.5% R-125/39.5% CF3I) was part of this study but will not be covered since it does not contain a haloolefin component.

Acknowledgments

The authors would like to thank all the companies, people and AHRTI (Air-Conditioning Research Technology Institute with funding support from the US Department of Energy Building Technology Office and the project monitoring committee for the sponsorship and administration of this project. Authors would like to thank Xudong Wang (AHRI), Samuel Yana Motta (previously Honeywell), Ankit Sethi (Honeywell), Jian Sun Blanks (Chemours), Sarah Kim (previously Arkema), Robert Low (Koura), Jim Scott (AGC), Bad Boggess (Emerson), Joe Karnaz (Shrieve) and Ryan Stanton (Idemitsu).

Disclosure statement

The authors declare that there is no conflict of interest regarding the publication of this article.

Additional information

Notes on contributors

Steve Kujak

Stephen “Steve” Kujak, BS Chemistry, Full Member ASHRAE is the Director of Next Generation Refrigerant Research for Trane Technologies, La Crosse, WI.

Morgan Leehey

Morgan Herried Leehey, BS Chemistry, Associate Member ASHRAE is the Refrigerant Chemistry Technology Leader for Trane Technologies Materials & Chemistry Network of Excellence, La Crosse, WI.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 78.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.