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Inorganic and Nano-Metal Chemistry Volume 49, 2019 - Issue 12
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Articles

Synthesis, crystal structure, and photodegradation properties of a new multicore Zn(II) metal organic framework

Yifan YuKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, People’s Republic of China; View further author information
,
Ziao ZongKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, People’s Republic of China; View further author information
,
Chuanbin FanKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, People’s Republic of China; View further author information
,
Xiangmin MengShandong Provincial Key Laboratory of Biochemical Engineering, College of Marine Science and Biological Engineering, Qingdao University of Science and Technology, Qingdao, People’s Republic of ChinaView further author information
,
Xia ZhangKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, People’s Republic of China; Correspondence[email protected]
View further author information
&
Yuhua FanKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, People’s Republic of China; Correspondence[email protected]
View further author information
Pages 455-460 | Received 17 Aug 2018, Accepted 24 Aug 2019, Published online: 17 Sep 2019
 
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Abstract

A novel metal organic framework, namely, {[Zn3(btc)2(bimmb)2.5]·2H2O·CH3CN}n (1) (btc = 1,3,5-benzenetricarboxylic acid), bimmb = 1,4-bis(imidazol-l-ylmethyl) benzene), has been reasonably designed, successfully solvothermally synthesized, and characterized. The complex is characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, thermogravimetric analysis, and powder X-ray diffraction. Complex 1 exhibits a 5-nodal 3,3,4,4,6-connected 3D framework with a (5·6·7)2(52·8)2(52·92·102)2(53·82·9)2(54·62·72·84·92·11) topology. The photodegradation studies reveal that complex 1 displays highly sensitive photodegradation sensing toward methylene blue, rhodamine B, and methyl violet under UV irradiation.

Additional information

Funding

This work was supported by the Fundamental Research Funds for the Central Universities (No. 201822012), the National Natural Science Foundation of China (Nos. 21476218 and 21601171).

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