Abstract
Reaction between 2,4-dichlorophenylacrylic acid (HL) and triphenyltin (IV) hydroxide to yield the complex [(Ph3Sn)L]n (1). The complex has been characterized by elemental analysis, infrared spectrum and single crystal X-ray diffraction. The structural analysis shows that complex 1 possesses 1 D chain structure in which every tin atom is five coordinated. The 1 D chains linked by C(66)-H(66)·Cl(2) hydrogen bonds to aggregate in 2 D framework. Additionally, the PXRD, TG, and luminescent property were also investigated. The quantum chemistry calculations was performed with the Gaussian09 program.
Acknowledgments
We thank the National Natural Science Foundation of China (No. 21805110) for financial support.