Determination of Technetium-99 in Peat by Flow Injection–Inductively Coupled Plasma Mass Spectrometry

ABSTRACT

Here a new flow injection system is reported for the preconcentration of technetium by solid phase extraction. The system provides analyte preconcentration, reduces interferences from polyatomic ions, and prevents interaction of concentrated nitric acid with the inductively coupled plasma mass spectrometer. The volume of eluate was significantly reduced by collecting the eluate of the highest analyte concentration in an injection loop followed by transport to the spectrometer with dilute nitric acid. Due to the absence of a suitable standard reference material, the determination of technetium in peat was compared with liquid scintillation spectrometry.

KEYWORDS:

• Flow injection
• inductively coupled plasma mass spectrometry (ICP MS)
• technetium

Additional information

Funding

The research was supported by the National Science Center (Poland) grant no. N305 066936.