Changes in Microcrystalline Composition, Functional Groups and Combustion Characteristics of Coal in Coalfield Fire Area after Baking by Different Temperature Gradients

ABSTRACT

Once fires occur in a coalfield, large quantities of coal in the coalfield will be baked at high temperatures. The changes and differences in the microscopic and spontaneous combustion properties of coals in high-temperature environments (ambient temperature or even after high-temperature baking) in the fire zone have not been studied yet. In this paper, three types of different-rank coals were baked at five different temperatures to investigate their changes in microcrystalline compositions, functional groups and combustion characteristics. The following results were obtained. The temperature treatment causes damage to the microcrystalline structure of different-rank coals. As the baking temperature rises, the aromatic layer spacing decreases, while the ductility and stacking height gradually increase. The aromatic ether content and the aliphatic hydrocarbon content gradually decline, while the -COOH content goes first and then falls. The spontaneous combustion activities of coals around the fire area gradually weaken with the rise of baking temperature. This research is crucial for revealing the effect of temperature, especially fire baking, on the spontaneous combustion characteristics of coal.

KEYWORDS:

• Coalfield fire
• different gradient temperatures
• microcrystalline composition
• functional groups
• spontaneous combustion properties

Acknowledge

This research was supported by the National Natural Science Foundation of China (51904172, 51574279), the China Postdoctoral Science Foundation(2020M682209), the Research Fund of Key Laboratory of Safe and Effective Coal Mining (Anhui University of Science and Technology), Ministry of Education(JYBSYS2020102), Special science and technology project on achievement transformation and technical demand in the West Coast New Area of Qingdao (grant numbers 2019-36), and the Natural Science Foundation of Shandong Province (ZR2019QEE041). We also wish to thank SISTRANS Editorial Services for improving the language of this paper.