Abstract
Phosphorus (P) dynamics and availability in soils are influenced by P fertilization. This paper aimed to evaluate inorganic P fractions bonded to calcium (Ca), iron (Fe), and aluminum (Al), associating them with soil mineralogy. The experiment was carried out using an acidic kaolinitic–oxidic soil, located in an irrigated area cultivated with coffee plants (Coffee arabica L.), submitted to successive annual fertilizations with triple superphosphate doses of 0, 50, 100 200, and 400 kg ha−1 phosphorus pentoxide (P2O5) in randomized blocks with three replications. Phosphorus fractions were determined in soil samples collected at two depths, 0–10 and 10–20 cm, according to the methodology used by CitationChang and Jackson (1957). The inorganic P fractions presented the following sequence: P-Al > P-Fe > P-Ca. The dynamics of forms of inorganic P showed that P-Al is controlling the P bioavailability as a result of an acidic pH and a very simple and thermodynamically stable clay mineralogy, typical of very weathered and old tropical soils.
Acknowledgement
The authors thank the Brazilian Consortium for Research and Coffee Development (CBP&D-Café) for their support and the National Council of Scientific and Technological Development (CNPq) for granting the scholarship and financial support to carry out this research project.