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Ferroelectrics Volume 339, 2006 - Issue 1
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SECTION O: RELAXOR FERROELECTRICS

E-T Phase Diagrams for PbMg1/3Nb2/3O3-PbTiO3 Single Crystals

I. P. Raevski Physics Department and Research Institute of Physics, Rostov State University, Rostov on Don, 344090, Russia
,
A. S. Emelyanov Physics Department and Research Institute of Physics, Rostov State University, Rostov on Don, 344090, Russia
,
F. I. Savenko Physics Department and Research Institute of Physics, Rostov State University, Rostov on Don, 344090, Russia
,
S. I. Raevskaya Physics Department and Research Institute of Physics, Rostov State University, Rostov on Don, 344090, Russia
,
S. A. Prosandeev Physics Department and Research Institute of Physics, Rostov State University, Rostov on Don, 344090, Russia
,
E. V. Colla Department of Physics, University of Illinois at Urbana Champaign, Urbana, Illinois, 61801
,
D. Viehland Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia, 24061
,
W. Kleemann Angewandte Physik, Universität Duisburg-Essen, D-47048, Duisburg, Germany
,
S. B. Vakhrushev A. F. Ioffe Physical-Technical Institute, 194021 St., Petersburg, Russia
,
J. -L. Dellis LPMC, Universite de Picardie Jules Verne, 33, rue Saint Leu, F-80039, Amiens, France
,
M. el Marssi LPMC, Universite de Picardie Jules Verne, 33, rue Saint Leu, F-80039, Amiens, France
&
L. Jastrabik Institute of Physics AS CR, Na Slovance 2, 182 21 Prague 8, Czech Republic
 show all
Pages 137-146 | Received 26 Jan 2006, Published online: 09 Mar 2011
 
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Abstract

The bias field-temperature, E-T, phase diagram for 0.87PbMg 1/3 Nb 2/3 O 3 -0.13PbTiO 3 crystals has been obtained by using two different techniques, dielectric spectroscopy and elastic compliance. The temperature dependence of both the dielectric permittivity and elastic compliance provide a step corresponding to the phase boundary between the relaxor and ferroelectric phases. In comparison with the phase diagram of pure PbMg 1/3 Nb 2/3 O 3 , the result obtained shows an additional, nearly vertical line, which lies close to the Vogel-Fulcher temperature.

Acknowledgments

This study is partially supported by RFBR (grants 04-02-16103, 05-02-16399, 05-02-90568 NNS and 05-03-32214) and 1QS100100563 AV CR. I. P. R. appreciates a financial support from a Scientific Research Fellowship and hospitality of Laboratoire de Physique de la Mati'ere Condens'ee, Université de Picardie Jules Verne. I.P.R. and S.A.P. are grateful to Vitaliy Topolov, Vladimir Shvartsman, Pavel Timonin and Vladimir Sakhnenko for discussions.

Paper originally presented at IMF-11, Iguassu Falls, Brazil, September 5–9, 2005

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