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Ferroelectrics Volume 346, 2007 - Issue 1
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Original Articles

In Situ Raman Scattering Study on Successive Crystallization of Bulk BaTi2O5 Glass

Hiroki Taniguchi Materials and Structures Lab., Tokyo Institute of Technology, Nagatsuta, Midori, Yokohama, 226-8503, Japan
,
Jianding Yu Japan Aerospace Exploration Agency (JAXA) ISS Science Project Office, Tsukuba, 305-8505
,
Yasutomo Arai Japan Aerospace Exploration Agency (JAXA) ISS Science Project Office, Tsukuba, 305-8505
,
Toshirou Yagi Research Institute for Electronic Science, Hokkaido University, Sapporo, 060-0812
,
Desheng Fu Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST)
&
Mitsuru Itoh Materials and Structures Lab., Tokyo Institute of Technology, Nagatsuta, Midori, Yokohama, 226-8503, Japan
Pages 156-161 | Received 15 May 2006, Published online: 29 Mar 2007
 
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Abstract

Crystallization process of ferroelectric-based BaTi 2 O 5 -glass (BTO125-glass) is studied by Raman scattering. Spectral change observed in the present study clarifies successive occurrence of two metastable phases in the crystallization. Variations of spectral intensities on isothermal crystallization are analyzed using Johnson-Mehl-Avrami equation to reveal the crystallization process of each phase. From the result, a homogeneous 3-dimensional growth of α phase and surface 3-demensional growth of β phase are concluded to be taken place gradually in the crystallization.

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