1,459
Views
1
CrossRef citations to date
0
Altmetric
Research Article

Effects of low temperatures and high strain rates on the tensile properties of polyurethane polymers for adhesives

, , ORCID Icon, , , , & show all
Pages 2238-2259 | Received 16 Dec 2022, Accepted 10 Feb 2023, Published online: 02 Mar 2023

Figures & data

Table 1. Composition and appearance of polyurethane compounds.

Figure 1. Viscoelastic characteristics of polyurethane compounds with respect to temperature: (a) storage modulus E’, (b) loss modulus E”, and (c) loss factor tan δ.

Figure 1. Viscoelastic characteristics of polyurethane compounds with respect to temperature: (a) storage modulus E’, (b) loss modulus E”, and (c) loss factor tan δ.

Figure 2. (a) Configuration and dimensions of specimen, (b) specimen for quasi-static tensile tests, and (c) specimen for high-strain-rate tensile tests.

Figure 2. (a) Configuration and dimensions of specimen, (b) specimen for quasi-static tensile tests, and (c) specimen for high-strain-rate tensile tests.

Figure 3. Mechanical material testing machine with a temperature chamber (above: overall view, below: close-up view of air flow system and specimen holder).

Figure 3. Mechanical material testing machine with a temperature chamber (above: overall view, below: close-up view of air flow system and specimen holder).

Figure 4. Hydraulic high-speed tensile testing machine with a temperature chamber.

Figure 4. Hydraulic high-speed tensile testing machine with a temperature chamber.

Figure 5. Typical SS curves of each polyurethane compound under static loading conditions: (a) RT, (b) −10°C, and (c) −40°C.

Figure 5. Typical SS curves of each polyurethane compound under static loading conditions: (a) RT, (b) −10°C, and (c) −40°C.

Figure 6. (a) Tensile strength and (b) elongation of each polyurethane compound under static loading conditions.

Figure 6. (a) Tensile strength and (b) elongation of each polyurethane compound under static loading conditions.

Figure 7. Typical SS curves of each polyurethane compound under high-strain-rate loading conditions: (a) RT, (b) −10°C, and (c) −40°C.

Figure 7. Typical SS curves of each polyurethane compound under high-strain-rate loading conditions: (a) RT, (b) −10°C, and (c) −40°C.

Figure 8. (a) Tensile strength and (b) elongation of polyurethane compounds under high-strain-rate loading conditions.

Figure 8. (a) Tensile strength and (b) elongation of polyurethane compounds under high-strain-rate loading conditions.

Figure 9. Deformation of PUC1 during high-speed tensile tests: (a) RT and (b) −40°C.

Figure 9. Deformation of PUC1 during high-speed tensile tests: (a) RT and (b) −40°C.

Figure 10. Deformation of PUC3 at high-speed rate tensile test at the temperature of – 40°C.

Figure 10. Deformation of PUC3 at high-speed rate tensile test at the temperature of – 40°C.

Figure 11. (a) Global and local SS curves of PUC3 at a temperature of −40°C under high-strain-rate conditions. The numbers on the SS curves correspond to the image numbers in . (b) Elongation at different measurement points (i.e. maximum ε1 and ε2) versus temperature.

Figure 11. (a) Global and local SS curves of PUC3 at a temperature of −40°C under high-strain-rate conditions. The numbers on the SS curves correspond to the image numbers in Figure 10. (b) Elongation at different measurement points (i.e. maximum ε1 and ε2) versus temperature.

Figure 12. Time variation of global and local strain of PUC3 at a temperature of −40°C under high-strain-rate conditions. The numbers on the curves correspond to the image numbers in .

Figure 12. Time variation of global and local strain of PUC3 at a temperature of −40°C under high-strain-rate conditions. The numbers on the curves correspond to the image numbers in Figure 10.

Figure 13. (a) Phase ratios and (b) relaxation times of polyurethane compounds evaluated by pulse NMR.

Figure 13. (a) Phase ratios and (b) relaxation times of polyurethane compounds evaluated by pulse NMR.