Morphology and Properties of Poly(vinyl alcohol)/MMT Nanocomposite Prepared by Solid-state Shear Milling (S³M)

Abstract

Poly(vinyl alcohol) (PVA)/montmorillonite (MMT) nanocomposites were prepared by combining solid-state shear milling (S³M) technology with melt intercalation. Compared with the composite obtained by simple melt intercalation, more MMT layers were exfoliated and apparently oriented along the injection molding direction in the nanocomposite prepared by combining S³M technology and melt intercalation, which greatly increased the orientation degree of MMT, resulting in the greater interactions between PVA and MMT layers. Simultaneously, this also promoted the orientation of PVA molecules and produced effective nucleation of the crystallization of PVA. Consequently, the thermal stability and mechanical properties of PVA were obviously improved. For instance, when the MMT content was 3 wt%, the tensile strength and modulus of the nanocomposite with MMT prepared by S³M were 98.9 MPa and 3.1 GPa, respectively, increasing by 52% and 63.2% compared with PVA.

Keywords:

• crystallization
• melt processing
• MMT
• nanocomposite
• poly(vinyl alcohol)
• solid-state shear

Acknowledgments

This research was supported by the National Natural Science Foundation of China (50833003, 51010004) and the International Collaboration Program from the Ministry of Science & Technology of China (2010 DFA54460).