Kinetics Study of the Thermal Decomposition of Post-consumer Poly(Ethylene Terephthalate) in an Argon Atmosphere

Abstract

The thermal decomposition of post-consumer samples of a carbonated water bottle made of poly(ethylene terephthalate), PC-PET, was examined by linear temperature programing under an argon atmosphere to determine its mass loss kinetics. A simple kinetic model, called the first order pseudo single-component model, was used. The total weight-loss of each sample assumed to be in two periods, with each period corresponding to a one step decomposition of the PC-PET to volatiles. Three methods for determining the kinetic parameters by thermal gravimetric analysis were examined: differential analysis at a constant heating rate (differential), temperatures of a given conversion at a number of heating rates (isoconversional), and the maximum rate at multiple heating rates (peak temperature). The latter two multiple heating rates methods results were comparable to each other but they were not in agreement with the results from the differential method. The results of the differential method were insensitive to the heating rate and consistent with kinetics data reported in the literature for PET.

Keywords:

• Post-consumer poly(ethylene terephthalate) (PC-PET)
• thermal decomposition
• kinetic modeling
• isoconversional degradation
• decomposition peak temperature
• differential kinetics of thermal degradation

Acknowledgments

This project was based upon work supported by the National Institute of Food and Agriculture, U.S. Department of Agriculture, Evans-Allen project number SCX-311-21-17.