Two-photon absorption properties of D-A-D type chromophores containing tetraphenylethylene and triphenylamine moieties: a close look at the effects of the strength, position and number of donors

ABSTRACT

The two-photon absorption (TPA) properties of a series of D-A-D type chromophores containing tetraphenylethylene (TPE) and triphenylamine moieties have been investigated employing the density functional response theory in combination with the polarisable continuum model. Special emphases are placed on the effects of the strength, position and number of donors on TPA. Our calculations demonstrate that the TPA intensity enhances with the increase of the electron-donating ability of the substituents on the triphenylamine unit, which is consistent with experimental observations. It is shown that the position of donors has an important effect on TPA. The donor on the side position of TPE unit decreases the TPA cross section, thereby more donors could not necessarily produce stronger TPA. The cis-trans isomerism effect is also explored and it is found that all the cis structures have lower TPA intensities than those of corresponding trans forms. By considering a different number of donors on TPE and triphenylamine unit respectively, it is interesting to find that the structure with one terminal donor on TPE and two donors on triphenylamine unit has the largest TPA cross section. The few-state model and the natural bond orbital charge analysis are used to explore the reason behind it.

GRAPHICAL ABSTRACT

KEYWORDS:

• Two-photon absorption
• tetraphenylethylene
• triphenylamine
• donor position
• donor number

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Shandong Provincial Natural Science Foundation, China [grant number ZR2014AM026]; and Taishan Scholar Project of Shandong Province, China.