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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 15
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Original Articles

SDS/Ac2O/H2O: Surfactant‐Mediated Cleavage of Imines with Acetic Anhydride to Carbonyls and Acetanilides in Water

Saikat Das Sharma Synthetic Organic Chemistry Division, Regional Research Laboratory, Jorhat, Assam, India
,
Pranjal Gogoi Synthetic Organic Chemistry Division, Regional Research Laboratory, Jorhat, Assam, India
,
Monalisa Boruah Synthetic Organic Chemistry Division, Regional Research Laboratory, Jorhat, Assam, India
&
Dilip Konwar Synthetic Organic Chemistry Division, Regional Research Laboratory, Jorhat, Assam, IndiaCorrespondence[email protected]
Pages 2473-2481 | Received 05 Dec 2006, Published online: 09 Aug 2007
 
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Abstract

Surfactant (SDS)‐mediated cleavage of imines was achieved with acetic anhydride to the corresponding carbonyls (aldehydes and ketones) and acetanilides in water at 25–30°C with very good to excellent yields, thus contributing significantly to the green chemistry concept.

Acknowledgement

The authors acknowledge the director and the Analytical Division of Regional Research Laboratory (RRL), Jorhat, Assam, India, for their help. Also, Saikat Das Sharma and Pranjal Gogoi thank the Council of Scientific and Industrial Research (CSIR), New Delhi, for the grants of Junior Research Fellowships.

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