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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 10
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Original Articles

FeCl3‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols

, , &
Pages 1617-1628 | Received 08 Oct 2007, Published online: 24 Apr 2008
 

Abstract

FeCl3‐catalyzed nucleophilic substitution reaction of Baylis–Hillman adducts with alcohols is described. The present protocol allows for the efficient syntheses of many kinds of functional ethers. This conversion is also a green route because water is the only side product.

Acknowledgment

We thank the National Natural Science Foundation of China (Nos. 20472048 and 20572068) for support of this work.

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