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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 10
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Original Articles

FeCl3‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols

Xueshun Jia Department of Chemistry, Shanghai University, Shanghai, ChinaCorrespondence[email protected]
,
Peichao Zhao Department of Chemistry, Shanghai University, Shanghai, China
,
Xiaotao Liu Department of Chemistry, Shanghai University, Shanghai, China
&
Jian Li Department of Chemistry, Shanghai University, Shanghai, China
Pages 1617-1628 | Received 08 Oct 2007, Published online: 24 Apr 2008
 
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Abstract

FeCl3‐catalyzed nucleophilic substitution reaction of Baylis–Hillman adducts with alcohols is described. The present protocol allows for the efficient syntheses of many kinds of functional ethers. This conversion is also a green route because water is the only side product.

Acknowledgment

We thank the National Natural Science Foundation of China (Nos. 20472048 and 20572068) for support of this work.

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