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Journal of Coordination Chemistry Volume 59, 2006 - Issue 7
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Original Articles

Synthesis, crystal structure and magnetic properties of a one-dimensional chain polymer, [Ni(IM2-Py)2(NO3)](NO3)

Yufang Wang Department of Chemistry, Luoyang Teacher's College, Luoyang 471022, P.R. China; College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002, P.R. China
,
Liya Wang Department of Chemistry, Luoyang Teacher's College, Luoyang 471022, P.R. ChinaCorrespondence[email protected]
,
Lufang Ma Department of Chemistry, Luoyang Teacher's College, Luoyang 471022, P.R. China
&
Kai Jiang College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002, P.R. China
Pages 705-711 | Received 24 Nov 2004, Accepted 21 Apr 2005, Published online: 22 Aug 2006
 
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Abstract

A novel complex [Ni(IM2-Py)2(NO3)](NO3), where IM2-Py is 2-(2′-pyridyl)-4,4,5,5-tetramethyl-2-imidazoline-1-oxyl, has been synthesized and characterized structurally and magnetically. The structure consists of [Ni(IM2-Py)2(NO3)]+ and a anion. The nickel(II) is in a distorted octahedral environment with four nitrogen atoms from two IM2-Py units and two oxygen atoms from a anion. The units of [Ni(IM2-Py)2(NO3)]+ were connected as a one-dimensional polymer by intermolecular interactions. Variable temperature magnetic susceptibility data show antiferromagnetic interactions between the nickel(II) and imino nitroxide radicals.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20471026) and the Natural Science Foundation of Henan province (No. 0311021200).

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