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Journal of Coordination Chemistry Volume 62, 2009 - Issue 24
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Original Articles

Hydrothermal syntheses and characterizations of two new hydrogen bond-supported supramolecular compounds based on polyoxometalates

Shu-Yun Shi Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, China; Department of Environmental Engineering, Jilin Normal University, Siping, 136000, China
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Jia-Ning Xu Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, China
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Wen-Ying MA Department of Applied Chemistry and Pharmacy, Zhuhai College, Jilin University, Zhuhai, 519000, China
,
Xiao-Bing Cui Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, ChinaCorrespondence[email protected]
,
Yan Wang Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, China
,
Guo-Wu Wang Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, China
&
Ji-Qing Xu Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, ChinaCorrespondence[email protected]
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Pages 3885-3894 | Received 08 Apr 2009, Accepted 08 Jun 2009, Published online: 22 Sep 2010
 
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Abstract

Two new polyoxometalates [HN(C2H5)3]3[PMo12O40] (1) and [NH2(C2H4NH3)2]2[Mo5P2O23] (2) have been hydrothermally synthesized and characterized by IR, UV-Vis, XPS spectra, TG analyses, and single crystal X-ray diffraction. Crystal data for 1: monoclinic, space group C2/c, a = 24.651(5) Å, b = 10.822(2) Å, c = 22.413(5) Å, β = 120.37(3)°, and V = 5158.7(18) Å3; for 2: triclinic, space group P-1, a = 9.821(2) Å, b = 9.948(2) Å, c = 14.687(3) Å, α = 95.490(3)°, β = 98.870(3)°, γ = 95.710(3)°, and V = 1401.7(5) Å3. The crystal structure analyses reveal complex hydrogen bonds in both 1 and 2 in 3-D supramolecular arrays constructed from different polyoxoanions and organic ligands.

Acknowledgment

This work was supported by the National Natural Science Foundation of China (Grant Nos 20571032 and 20333070).

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