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Original Articles

Two threefold interpenetrated metal-organic frameworks (CoII, NiII) with (65.8) topology constructed from biphenyl-3,4′-dicarboxylic acid

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Pages 763-771 | Received 19 Jul 2012, Accepted 01 Oct 2012, Published online: 12 Mar 2013
 

Abstract

[Co(bmib)(bpda)]·H2O (1) and [Ni(bmib)(bpda)] (2) (H2bpda = biphenyl-3,4′-dicarboxylic acid; bmib = 4,4′-bis(2-methylimidazol-1-ylmethyl)benzene) were synthesized under hydrothermal conditions. The structures have been determined by single-crystal X-ray diffraction analyzes and further characterized by elemental analyzes, IR, PXRD, and TGA. Compounds 1 and 2 possess a threefold interpenetrated (65.8) architecture that incorporates left- and right-handed helical chains. The difference of angles between the coordination spacers in 1 and 2 causes a large difference along the c-axis.

Acknowledgements

The work was supported by financial support from the Natural Science Foundation of China (Grant No. 21101097), Natural Science Foundation of Shandong Province (ZR2010BQ023), and Qilu Normal University is acknowledged.

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