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Journal of Coordination Chemistry Volume 67, 2014 - Issue 15
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Articles

Synthesis and characterization of a new cadmium complex based on 1,1-diamino-2,2-dinitroethylene

Qian SunSchool of Chemical Engineering, Northwest University, Xi’an, ChinaView further author information
,
Ze LiCollege of Chemistry & Materials Science, Northwest University, Xi’an, ChinaView further author information
,
Xiang GongSchool of Chemical Engineering, Northwest University, Xi’an, ChinaView further author information
,
Zhe GaoSchool of Chemical Engineering, Northwest University, Xi’an, ChinaView further author information
,
Kang-Zhen XuSchool of Chemical Engineering, Northwest University, Xi’an, ChinaCorrespondence[email protected]
View further author information
,
Ji-Rong SongSchool of Chemical Engineering, Northwest University, Xi’an, ChinaView further author information
&
Feng-Qi ZhaoXi’an Modern Chemistry Research Institute, Xi’an, ChinaView further author information
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Pages 2576-2582 | Received 04 Apr 2014, Accepted 21 Jul 2014, Published online: 26 Aug 2014
 
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Abstract

A new cadmium complex of 1,1-diamino-2,2-dinitroethylene (FOX-7) was synthesized and structurally determined. Central Cd2+ is coordinated by six nitrogens from four NH3 molecules and two FOX-7− anions to form an octahedral structure. The thermal decomposition of Cd(NH3)4(FOX-7)2 was studied with differential scanning calorimeter and TG–DTG methods. The apparent activation energy and pre-exponential constant of the exothermic process are 220.6 kJ M−1 and 1017.86 s−1, respectively. Cd(NH3)4(FOX-7)2 is sensitive.

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Funding

Funding. This investigation received financial assistance from the National Natural Science Foundation of China [grant number 21241003], [grant number 20803058]; the Science and Technology Research and Development Program of Shaanxi Province [grant number 2013K02-25]; Education Committee Foundation of Shaanxi Province [grant number 2013JK0697].

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