Abstract
[MnIIxFeII1−x(H2O)6][LiFeIII(ox)3] (with 0 ≤ x ≤ 1) crystallizes in the space group P31c with a = 9.341(3) Å, c = 10.226(3) Å, c/a = 1.0947, and V = 772.8(5) Å3 for Z = 2. The compound has a layered structure with two enantiomeric layers per unit cell. The layers are built up by an iron and lithium oxalate framework with intercalated M(II)-water octahedra of the formula [MnIIxFeII1−x(H2O)6][MIMIII(ox)3]. The value of x cannot be specified at present. The structure displays intermolecular hydrogen bonding between the layers.
Disclosure statement
No potential conflict of interest was reported by the authors.