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Journal of Coordination Chemistry Volume 69, 2016 - Issue 9
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Articles

Synthesis and characterization of diiron ethanedithiolate complexes with monosubstituted phosphine ligands

Xiao-Qin ChenCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, China
,
Xu-Feng LiuCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, ChinaCorrespondence[email protected]
,
Zhong-Qing JiangCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, China
,
Ying-Xin ZhangCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, China
,
Xie LiCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, China
,
Xiao-Ning TianCollege of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, China
&
Xing-Hai LiuCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China
 show all
Pages 1439-1446 | Received 18 Oct 2015, Accepted 23 Mar 2016, Published online: 19 May 2016
 
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Abstract

Reactions of (μ-edt)Fe2(CO)6 (edt = SCH2CH2S) (1) with the monophosphine ligands Ph2PCH2Ph, Ph2PC6H11, Ph2PCH2CH2CH3, or P(2-C4H3O)3 in the presence of Me3NO∙2H2O afforded (μ-edt)Fe2(CO)5L [L = Ph2PCH2Ph, 2; Ph2PC6H11, 3; Ph2PCH2CH2CH3, 4; P(2-C4H3O)3, 5] in 70–88% yields. Complexes 2–5 were characterized by spectroscopy and single crystal X-ray diffraction analysis. The phosphorus of 2–5 is in an apical position of the distorted octahedral geometry of iron.

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