Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 71, 2018 - Issue 15
Submit an article Journal homepage
83
Views
1
CrossRef citations to date
0
Altmetric
Articles

Isolation of a bis(silyl)palladium complex and Si–Si bond formation on a mononuclear palladium complex

Yan Rong SuKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, China
,
Jia Wei LiuKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, China
,
Fei Fei JuKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, China
,
Jing Wen XuKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, China
,
Qing LuKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, China
,
Kang XiaoKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, ChinaCorrespondence[email protected]
,
Shi Wang
&
Yong Hua LiKey Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, ChinaCorrespondence[email protected]
 show all
Pages 2457-2464 | Received 12 Jan 2018, Accepted 04 May 2018, Published online: 14 Jun 2018
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Treatment of a chelating silane 1-(dimethylsilyl)-2-silylbenzene (4) with Pd(PEt3)4 in the ratio of 2:1 selectively afforded a unique mononuclear palladium complex [{1,2-C6H4(SiMe2)(SiH)}2Pd(PEt3)2] (6), which was formed by two Si–Si coupling reactions between the SiH2 groups and the SiMe2 moieties from two hydrosilane ligands. Complex 6 was structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies and is one of the very few examples of cis-bis(silyl)palladium(II) complexes containing in situ formed Si–Si single bonds.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 1,057.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.